Thermal Dehydrochlorination of Poly(vinyl chloride) by FT-IR Spectroscopy.

FT-IR Photoacoustic Spectroscopy

Thermal Degradation of Polyvinyl Chloride

A survey is given of the recent advances in the study of and the present knowledge of the thermal degradation of polyvinyl chloride. The sites for initiation of the thermal degradation, the mechanism of the dehydrochiorination, the discolouration of PVC by heat and the influence of plasticizers on the rate of degradation are discussed.

FT-IR Spectroscopy in Medicine

Infrared spectroscopy has been widely applied for the characterisation of various substances. Due to its sensitivity to the chemical information and architecture of the molecule, infrared spectroscopy can play an important role in new applications such as in the life-science field and not only in the traditional fields of physics and chemistry. Spectroscopic techniques are simple, reproducible,...

effect of water on hema conversion by ft-ir spectroscopy

objective: the use of hema as a biocompatible material in dentin bonding systems and its potential for clinical applications has been well established. excess water can affect conversion of bonding resins. the aim of this study was to survey the effect of water on the degree of conversion of hema by fourier transform infra-red spectroscopy (ft-ir). materials and methods: in this experimental st...

Kinetic Model for Thermal Dehydrochlorination of Poly(vinyl chloride)

In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal dehydrochlorination of two different samples of PVC. It has been observed that this dehydrochlorination is complex and involves two different processes. A model that accounts for the entire dehydrochlorination is proposed. This model involves nucleation and growth and diff...